The furnace was then cooled to room temperature to obtain COF films. Film morphology was imaged using a NIKON Eclipse LV-100 optical microscopy. The material structure of COF films was studied by using a Horiba Raman spectroscope with laser excitation at 532 nm at room temperature.
A COF film grown on a piece of Cu foil is used as working electrode, and an Ag/AgCl (saturated KCl) electrode and a piece of Pt foil are used as reference electrode and counter electrode respectively. The film thickness is ~13 nm.
COF-999 is an exceptional material for the capture of CO 2 from open air as evidenced by its cycling stability, facile uptake of CO 2 (reaches half capacity in 18.8 min) and low regeneration temperature (60 °C).
COF materials are one of the most recently developed branches of reticular chemistry with an objectively real potential to motivate the sequestration of emitted CO 2.
A method is reported that produces highly strong, tough and elastic 2D COF films, using a sacrificial go-between, which endows them with new properties.
(26) COFs were thus a new class of highly porous organic polymers with 2D or 3D network topologies, similar to metal–organic frameworks, but composed solely of light elements and potentially more robust in nature.
Here, a general strategy is developed to improve the energy storage capability of COF-based electrodes by integrating COFs with carbon nanotubes (CNT). These COF composites feature an abundance of redox …
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COF-999 is an exceptional material for the capture of CO2 from open air as evidenced by its cycling stability, facile uptake of CO2 (reaches half capacity in 18.8 min) and …
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COF materials are one of the most recently developed branches of reticular chemistry with an objectively real potential to motivate the sequestration of emitted CO 2. COF materials have been developed that simultaneously …
The PM-TPI COF and NT-TPI COF films are promising materials for electrochemical energy-storage applications owing to their hierarchical porous crystal structure …
Wafer-scale 2D COF films with different structures have been successfully synthesized by adjusting their building blocks, suggesting its generic applicability.
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The 2D COF, constructed by condensing p-phenylenediamine (DAB) with 1,3,5-triformylphlorogluciol (TFP), was solvothermally grown and formed oriented thin films on several substrates. Two strategies were developed to fabricate well …
Nature - A method is reported that produces highly strong, tough and elastic 2D COF films, using a sacrificial go-between, which endows them with new properties, enhances …
This Perspective discusses the advances in this field of energy research while highlighting the underlying peremptory factors for the rational design of readily tunable COF photoabsorber–cocatalyst systems for optimal …
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In addition, three procedures for synthesizing TpPa-1 COF were compared: conventional hydrothermal synthesis (HT), microwave-assisted synthesis (MW) and mechanochemical synthesis (MC) which directly avoids …
Researchers can explore the vast landscape of COF design, seeking novel structures with targeted properties for different applications of energy storage and beyond. The …
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